Souza Neto, J.A. (1); J.M. Legrand (2); Ph. Sonnet (1).
* Financial support: CNPq / UCL.
Fluid inclusions were investigated in quartz and calcite in three samples: a barren quartz vein, a gold-bearing quartz-sulphide-calcite vein and a calc-silicate rock. The objective is to compare the fluid in the veins and in the calc-silicate rock. The inclusions are classified as primary and pseudosecondary (Roedder, 1984, p. 12-26) and have been divided into two groups:
1) Carbonic inclusions: this type shows regular forms (negative crystal shape) with size between 10 and 15 microns. Two phases (liquid and vapor) or one phase (liquid) are present at room temperature. The degree of fill by the liquid phase is about 80 %. It is the most abundant type.
2) Aqueous-saline inclusions: this type has irregular forms and size ranging from 8 to 20 microns. Two phase (liquid and vapor) and rarely three phase inclusions (liquid, vapor and solid) are present at room temperature. The solid phase is probably halite. The degree of fill by the liquid phase is generally 90 %, but can vary down to 60 %.
Fusion temperature (Tf) obtained for carbonic inclusions varies from -57.3 to -56.0oC (barren quartz vein and quartz from the calc-silicate rock), which suggests a fluid composition close to pure CO2 (Angus et al., 1976). Homogenization temperature (Th) in the quartz vein has a normal distribution, with a range from -25.4 to 30.4oC, and a peak of distribution at 5.0oC. In the quartz from the calc-silicate rock, the range is from 2 to 29.8oC, with a peak at 25oC. Tf and Th values indicate a possible content of CH4 in the range 3.0 to 4.5 mol. % (Heyen et al., 1982).
Aqueous-saline inclusions in quartz vein show a eutectic temperature (Te ) with a range from -64.2 to -34.7oC and maximum frequency at -52.5oC (Figure 1). For quartz from the calc-silicate rock, Te varies from -36.2 to -53.8oC, with a maximum frequency at -52.5oC. In the quartz-sulphide-calcite vein, only one Te was measured and the value is -48.7oC. These data indicate more complex brines within a polycomponent salt system, probably a H2O-NaCl-KCl-CaCl2-MgCl2 system (Crawford, 1981). Eutectic temperatures below -60oC reveal other elements into the system, possibly Fe (Linke, 1958). The range of ice melting temperatures (Tm ice ) is wide, from -46.4 to 1.1oC, with a maximum frequency at -2.5oC. For quartz in the calc-silicate rock, these values are between -21.5 and -1.6oC with a peak at -5oC. The only value observed for the quartz-sulphide-calcite vein is -9.2oC. Finally, the homogenization temperature (Th) occurs in an interval from 84.8 to 529.1oC, with three peaks in the distribution at 140, 260 and 340oC. In the case of the calc-silicate rock, these values are between 140.6 and 351.6oC, with a maximum frequency at 260oC. For the quartz-sulphides-calcite vein, Th has a range from 225.7 to 321.9oC with a peak at 220oC.
The data have been interpreted using the FLINCOR software, version 1.4 (Brown, 1989) and equations of Brown & Lamb (1989). The interval for the homogenization temperatures (from -25.4 to 30.4oC) for carbonic inclusions reflects a variation in the fluid density from 1.057 g/cm3 to 0.575 g/cm3. It reveals a variation of trapping pressure (Bottinga & Richet, 1981), and can represent a post-trapping re-equilibration of pressure. For calc-silicate rock specifically, the density is 0.712 g/cm3 corresponding to Th value of 25oC.
In the quartz veins values of Tm ice (-2.5oC) and Th (140, 260 and 340oC) yielded a common salinity value of 4.1 wt.% NaCl and density values of, respectively, 0.957 g/cm3, 0.820 g/cm3 and 0.666 g/cm3. The inclusions in quartz from the calc-silicate rock show a salinity of 7.8 wt.% NaCl (Tmice = -5oC) and density of 0.861 g/cm3 (Th = 260oC). For the inclusions in the quartz-sulphide-calcite vein the salinity is 13.1 wt.% NaCl (Tm ice = -9.2oC) and the density is 0.948 g/cm3 (Th = 220oC). These values were obtained using the H2O-NaCl equivalent system.
In a previous work (Souza Neto, 1995), a geochemical balance study involving the calc-silicate rocks and their protoliths (marbles and alkaline rocks) provided evidence that the metasomatic fluids, during the formation of the calc-silicate rocks, had been able to carry Ca, Mg, Fe, K and Si. The presence of the same elements (Ca, Mg, Fe and K) in these fluids is shown by the relatively low eutectic temperature for aqueous-saline inclusions. This is observed in the veins as well as in the calc-silicate rocks.
This study suggests that there is a compositional similarity between the metasomatic fluids which caused the formation of the calc-silicate rocks and the fluids present during the formation of the veins. These fluids had a composition involving CO2 and H2O, with probably dissolved Ca, Mg, Fe and K.
Figure 1-Histogram of eutectic temperatures (Te) for aquo-saline inclusions. The lowest values are indicative of CaCl2 and/or MgCl2-bearing brines. n is number of measures.