M.S. Research (UNM, 1999-2001): Two Projects

Link to the Colorado Front Range tectonics project

Link to the aluminum silicate oxygen isotope project (also in the Colorado Front Range)

 
 

M.S. committee (Jedi Council):

Dr. Jane Selverstone: Metamorphic pet., Tectonics, Swiss chocolate
Dr. Zach Sharp: Stable isotopes, Thermogoddamics, Canine connoisseur
Dr. Karl Karlstrom: Structure, Tectonics, Grand Canyon guru
Dr. Cornelis Klein: BIF's, Your mineralogy book, Mr. Mineral 

M.S. research interests included: 

  • Proterozoic geology of N. Colorado (Colorado Province). 
  • Continental crustal growth processes in the Proterozoic. 
  • Oceanic crust petrogenesis (modern), basalt chemistry.
  • Ophiolites, ocean floor metamorphism and fracture zone tectonics.
  • Metamorphic petrology- Shear zone kinematics, metamorphism, and deformation. 
  • Stable isotope geochemistry- Oxygen isotopes in silicates and more- See the UNM isotope lab?


Colorado Front Range Project

The work I completed for a M.S. complemented part of a larger NSF-funded project that P.I. Dr. Jane Selverstone (UNM), Dr. G. Lang Farmer (CU-Boulder), and John Aleinikoff (USGS-Denver) have been working on for several years. The project involves understanding the tectonic evolution of the Paleoproterozoic Colorado province by looking at exposures in the northern Front Range of Colorado.

I focused on a research area west of Ft. Collins, Colorado, in Paleoproterozoic supracrustal and igneous rocks. I concentrated on an east-west striking package of deformed mafic metavolcanic rocks (now lower amphioblite grade) that is surrounded by less-deformed metasediments to the north and south. The mafic rock package hosts a sub-vertical shear zone and contains what we interpret to be dismembered ophiolitic lithologies. The presence of gabbros and clinopyroxenites with preserved yet highly deformed igneous assemblages allows us to 'look through' both 1.7 and 1.4 Ga metamorphic episodes and document igneous deformation that pre-dates the later metamorphic episodes. Igneous fabrics include spectacularly deformed clinopyroxenes that define horizontal lineations throughout the shear zone. Similar fabrics and microstructures are known only from modern transform-fracture zones and obducted transform fault ophiolites, and lead us to believe that the Buckhorn Creek shear zone may have originated in such an environment. We believe this mafic shear zone, and likely others in the northern Front Range, are reactivated transform fracture zones that developed during ~2.1 Ga rifting of the Wyoming, Superior, and a third Archean province.

What I refer to as the Buckhorn Creek shear zone (field shots) runs continuously for at least twenty kilometers from Redstone Canyon (Horsetooth Reservoir quad) through the Buckhorn and Crystal Mountain quads, and possibly into the Pingree Park quad where the cross-cutting relationship with the Skin Gulch shear zone is unclear.


Kinematics: In thin section I have documented both igneous and metamorphic lineations. 

Igneous lineations are defined by elongate clinopyroxenes from deformed gabbros, and also from relatively undeformed clinopyroxenes in clinopyroxenites (see image below). In both rock types the pyroxenes define horizontal lineations throughout the shear zone. Based on well-developed exsolution lamellae developed along the length of the elongate pyroxenes, we believe the pyroxenes first deformed during crystallization in supra-solidus conditions, and then the lamellae developed during cooling. 



 

The metamorphic lineations consist of amphiboles in steep and shallow orientations, commonly within a single thin section. It is not easy to determine which lineation is related to 1.7 or 1.4 Ga deformation, and my work only touches on understanding this later history. We think the steep lineation is likely related to 1.4 Ga contraction. 

XRF: I conducted whole-rock analyses for major and trace element determinations on over 30 samples from the mafic body and surrounding 'lenses'. All of the samples analyzed are clearly tholeiitic, and trace element discriminant diagrams consistently indicate an oceanic origin, but not a unique one. 
 

 
 

It was only when we started to compare our analyses with basalts from modern oceanic environments that we found similar geochemical trends with mid-ocean ridge and fracture zone basalts, and were easily able to distinguish our samples from trends developed in island-arc basalts. The modern data set was graciously taken (for free) from the RIDGEPET database , an impressive store-house of thousands of chemical whole-rock analyses provided by ODP, DSDP, and many other sources. An incredible amount of data can be down-loaded from the internet in a usable format in very short time periods. These data helped us do comparissons like the one below (e.g. TiO2 vs. MgO) using massive numbers of analyses.
 

Stable Isotopes: I have only analyzed a few mineral pairs from the amphibolites (where garnet occurs) and more from the metasediments (typically garnet +/- aluminosilicate assemblages) for thermometric determinations on samples from north, south and within the shear zone. Most of the stable isotope work was done on quartz veins (see below) rather than on the mafic rocks.

Microprobe: We've analyzed clinopyroxenes and also the exsolution lamellae from the mafic minerals. The exsolution lamellae analyses are consistenly sub-calcic, but are not pure orthopyroxene. 

My results rely heavily on geochemistry, field relations, and kinematics to try and determine the protolith origin, emplacement mechanisms, and accretionary history for this region of the Colorado province.
See publication list for references of this work.


Aluminosilicate Isotope Project

Another project that developed during my Master's research involved using oxygen isotopes to quantify equilibrium for the system andalusite + sillimanite. I used quartz veins that contained texturally equilibrated andalusite and sillimanite to test (1) whether or not a polymorphic fractionation of oxygen occurs in the Al2SiO5 system, and (2) Use the temperature constraints from quartz-Al2SiO5 oxygen isotope thermometry in conjunction with textural observations to constrain the location of the vein assemblages along the andalusite=sillimanite curve, allowing a determination of temperature AND pressure of vein formation (i.e. a stable isotope geothermobarometer). The vein localities are in the Front Range of Colorado where sillimanite and andalusite occur as intergrown crystals, locally exceeding 20 cm's in length (see photo below).

In several of the localities studied so far, muscovite and k-spar are both present, providing further petrogenetic constraints. Oxygen analyses of sillimanite and andalusite show no fractionation of 18O when in textural equilibrium, and preserve shifts when different generations of growth are evident. See the publications list for a PDF version of a recent article that appeared in American Mineralogist on this work. Dr. Zach Sharp and Dr. Jane Selverstone at the University of New Mexico, Albuquerque were involved with the research and funding of this project.

Here is a photo of one of the Colorado samples. The bladed mineral is sillimanite, reddish mineral is andalusite, and quartz is white. Not easily discernable are both muscovite and k-spar (Photo by Z. Sharp).

L. to R.: Aaron Cavosie, Mike Holdaway, and Toti Larson

Back to the Front Range Project

Other assorted links:

acavosie@geology.wisc.edu
Pictures of field area
Back to my home page


This site last updated: 7/20/01